yimmien
Molten Core Raider
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If you're only gonna play one, play AC4. It's pretty awesome.
If you've got room for 2-3, play AC2 and its sequels. The Ezio trilogy really is a memorable experience and now there's a remaster so it won't look awful by modern standards. Brotherhood is a great game and direct sequel to AC2, while Revelations is kinda iffy and mid but it combines the AC1 and AC2 storylines with you playing as both protagonists and going to the Middle-East.
If you like the series enough to keep going after that, almost the whole thing is worthwhile. Most of them are short and fly by. I'd do AC4 after the Ezio trilogy, then AC3 after that. Why? Because AC4 is actually a prequel to AC3, and AC3 starts with you playing as the son of the AC4 protagonist. After those AC Rogue is a very solid game with more pirate action. AC Unity gets slammed a lot but it's decent, covers the French Revolution, has a protagonist who tries to re-create Ezio's swagger and the single sexiest and most likeable female in the series IMO (not playable unfortunately). AC Syndicate is a step up from Unity and didn't get enough credit, solid game that's even better if you love London. After that the series switches to less AC and more open world adventure games, so they start doubling in length. Origins is a good time because of the Ancient Egypt setting and when it comes down to it, it might be the next one I strongly recommend after AC2 and 4. Basically doubles the length of earlier games. Then AC Odyssey has Ancient Greece and can be a lot of fun, skip the DLCs though. I'd skip Origins' DLCs too. Odyssey doubles the length of Origins and goes on too long, so only go on to that if you have the time. Finally there's AC Valhalla which doubles Odyssey's length and is boring AF unless you love Vikings. Like, really love Vikings. Not worth it. None of the spinoffs were worthwhile either IIRC.
Or ignore all of this and just play Black Flag. Skip through the present day crap and enjoy naval battles and pirating.