I haven't been following all of this but I'll add that
- Plywood is really no more or less ugly than anything else, completely dependent on how you finish it and use it. The Baltic Birch stuff sands and stains nicely and you can always do a veneer of something around the edge if you want to hide it or do a roundover on the edges. It is a very stable material. This isn't OSB or the sanded plywood stuff.
- If you go the pine route you're still going to have to figure out how to build a shelf. One annoying thing about those plans you linked was just starting off with "Grab your 14" x 67" shelf" with no further information. Even the picture on his instructions shows a glued up shelf. So if you don't go with a sheet good that comes in a size you can cut down to 14" x 67" (plylwood sheets usually come in 4' x 8' or 2' x 4' so you'd be stuck going with the 4' x 8' but you'd probably want that for two shelves) you have to make one. That
usually involves combining a bunch of boards together.
Plywood tops or MDF tops on workbenches can be good because if they get dinged up or covered in stain or glue you can remove them and replace them with a fresh top. Otherwise you can build your bench out of laminating pine or whatever.
The 14" depth of the shelves and the bench is really inconvenient b/c either way you're out more than 1 sheet of ply. Even if they were 12" you can't get 4 out of one sheet b/c of the kerf of whatever saw you're using. It'd be close. So two 3/4" glued and screwed to give you a beefy bench and regular 3/4" shelves.
Actually, the easiest way to do this is go find some scrap table and rip the top off and tear it down. I've got like 3 tables that could probably be repurposed. Or something from Lowe's or Ikea that is $20 a pop. Or Homegoods or whatever that craft store is where chicks find pillows that say "GIRLS NIGHT OUT!" and "THIS HOUSE BUILT ON LOVE, Y'ALL"
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