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Did you miss the transformation of his character during the movie? For whatever reason, Django's plight brought something out in him, and at least in the short term, his life became about helping Django. I don't really think either situation is terribly OOC, particularly the money. The death was... unsatisfying, but still fit fairly well with what was going on with the character. Coming from a starting point of mild disgust but ultimately neutral with regard to slavery, logically coming to the conclusion that he should probably "enslave" Django for his own benefits temporarily, and then spending enough time immersed in Django's story to the point where he could barely stomach Leo's mistreatment of his slaves allows his snap decision to kill Leo with his derringer to fit. He just stands there because he had already quickly thought out the repercussions, and he was ok with it. He knew Butch would gun him down, he just couldn't abide Leo living for one more moment.