Have we not mentioned
Spontaneanationyet? Paul F. Tompkins' very own interview/improvpodcast. PFT is the best guest for any comedypodcast(along with Kumail Nanjiani and Andy Daly). Spontaneanation has 2 distinct parts each episode. The first part is a "free form interview" with one celebrity. The previous guest will leave a question for the next guest(blind, not knowing who the guest will be). PFT asks the question and they have a conversation starting there that always veers off in to weird and hilarious directions.
Episode 9 with Michael Sheenwas particularly hilarious in this department, that dude is great.
After the interview they do a break, during which the guest will tell Paul a location. The rest of the show will be Paul and 3 other improv experts(you'll probably recognize a few from TV and other things) acting out a scene at that location, with things pulled from the interview thrown in to great effect. If you're a fan of "breaking" in sketch type shows it gets especially fun. They take a lot of delight in tripping each other up or just pointing out(in character) stupid things someone says. They're never full on Jimmy Falloning it, but there's a lot of off-mic laughter when this shit happens and it's hard not to laugh along.
"The Student Lounge at A Performing Arts High School" turns in to a full Hamlet situation with children trying to murder each other on stage at the behest of Nick Nolte. Every episode gets equally ridiculous.
It was a little shaky for the first episode or two maybe, but it found it's stride very quickly and it's fucking hilarious now.